Espaņol - English

Silvina C. Pellegrinet    pellegrinet@iquir-conicet.gov.ar



Curriculum Vitae



Selected Publications

α-Hydroxyacids accelerate the Diels-Alder reaction of dibutyl vinylboronate with cyclopentadiene: experimental results and mechanistic insights

Grimblat, N.; Sarotti, A. M.; Pisano, P. L.; Pellegrinet, S. C. New J. Chem., 2016, 40, 1966-1969.

 

Competing mechanisms for the reaction of dichloropropynylborane with 2-tert-butylbutadiene. Diels-Alder reaction versus alkynylboration

Vallejos, M. M.; Pellegrinet, S. C. RSC Adv., 2015, 5, 70147-70155. 

 

Diels-Alder reactions of pinacol alkenylboronates: an experimental and theoretical study

Vallejos, M. M.; Grimblat, N.; Pellegrinet, S. C. RSC Adv., 2014, 4, 36385-36400

 

Reactivity and Selectivity of Boron-Substituted Alkenes in the Diels-Alder Reaction with Cyclopentadiene. A Study of the Electron Charge Density and Its Laplacian

Vallejos, M. M.; Grimblat, N.; Pellegrinet, S. C.J. Phys. Chem. A, 2014, 118, 5559-5570. 

 

A Hydrogen Bond Rationale for the Enantioselective β-Alkenylboration of Enones Catalyzed by O-Monoacyltartaric Acids

Grimblat, N.; Sugiura, M.; Pellegrinet, S. C. J. Org. Chem.201479, 6754-6758.

 

[4 + 3] and [4 + 2] mechanisms of the Diels-Alder reactions of vinylboranes: an analysis of the electron charge density distribution

Vallejos, M. M.; Peruchena, N. M.; Pellegrinet, S. C.Org. Biomol. Chem. 2013, 11, 7953 - 7965.

 

Theoretical investigation of the Diels-Alder reactions of unsaturated boronates

Grimblat, N.; Pellegrinet, S. C. Org. Biomol. Chem., 2013,11, 3733 - 3741.

 

Application of the Multi-standard Methodology for Calculating 1H NMR Chemical Shifts

Sarotti, A. M.; Pellegrinet, S. C. J. Org. Chem., 2012, 77, 6059-6065.

 

A genome-wide regulatory framework identifies maize Pericarp Color1 (P1) controlled gene

Morohashi, K.; Casas, M. I.; Falcone-Ferreyra, M. L.; Mejía Guerra, M. K.; Pourcel, L.; Yilmaz, A.; Feller, A.; Carvalho, B.; Emiliani, J.; Rodriguez, E.; Pellegrinet, S.; McMullen, M.; Casati, P.; Grotewold, E. Plant cell, 2012, 24, 2745-2764.

 

Mechanistic Insights into the BINOL-Derived Phosphoric Acid-Catalyzed Asymmetric Allylboration of Aldehydes.

Grayson, M. N.; Pellegrinet, S. C.; Goodman, J. M., J. Am. Chem. Soc., 2012, 134, 2716-2722.

 

Evaluation of the use of mandelate derivatives to determine the enantiomeric purity and the absolute configuration of secondary cyclohexenols.

Sarotti, A. M.; Pisano, P. L.; Pellegrinet, S. C., Arkivoc 2011, vii, 343-357

http://pubs.rsc.org/en/content/articlelanding/2010/ob/c0ob00020e


Synthetic and computational studies on the tricarboxylate core of 6,7-dideoxysqualestatin H5 involving a carbonyl ylide cycloaddition-rearrangement.

Hodgson, D. M.; Villalonga-Barber, C.; Goodman, J. M.; Pellegrinet, S. C. Org. Biomol. Chem., 2010, 8, 3975-3984


A facile microwave-assisted Diels-Alder reaction of vinylboronates.

Sarotti, A. M.; Pisano, P. L.; Pellegrinet, S. C., Org. Biomol. Chem. 2010, 8, 5069-5073

http://pubs.rsc.org/en/content/articlelanding/2010/ob/c0ob00020e

 

Asymmetric Allylboration Reactions with Soderquist’s Chiral 10-Substituted-9-borabicyclo[3.3.2]decanes: A Theoretical Study.

Sarotti, A. M.; Pellegrinet, S. C., J. Org. Chem. 2009, 74, 3562-3565.
http://pubs.acs.org/doi/pdf/10.1021/jo900346u

 

An experimental/theoretical approach to determine the optical purity and the absolute configuration of endo- and exo-norborn-5-en-2-ol using mandelate derivatives.

Pisano, P. L.; Sarotti, A. M.; Pellegrinet, S. C., Tetrahedron Lett. 2009, 50, 6121-6125

http://dx.doi.org/10.1016/j.tetlet.2009.08.056

 

Mechanistic Insights into the Catalytic Asymmetric Allylboration of Ketones: Brønsted or Lewis Acid Activation?

Paton, R. S.; Goodman, J. M.; Pellegrinet, S. C., Org. Lett. 2009, 11, 37-40

http://pubs.acs.org/doi/pdf/10.1021/ol802270u

 

A MultiStandard Approach for GIAO 13C NMR Calculations.

Sarotti, A. M.; Pellegrinet, S. C. J. Org. Chem., 2009, 74, 7254-7260, J. Org. Chem. 2009, 74, 7254-7260
http://pubs.acs.org/doi/pdf/10.1021/jo901234h

 

Theoretical Study of the Asymmetric Conjugate Alkenylation of Enones Catalyzed by Binaphthols.

Paton, R. S.; Goodman, J. M.; Pellegrinet, S. C., J. Org. Chem. 2008, 73, 5078-5089
http://pubs.acs.org/doi/pdf/10.1021/jo8007463

 

An Exercise on Structure Elucidation based on a Tricky Aldol Reaction.

González Sierra, M.; Pellegrinet, S. C.; Colombo, M. I.; Rúveda, E. A., J. Chem. Ed. 2008, 85, 1094-1096

 

Studies on the Intramolecular Cyclizations of Bicyclic delta-Hydroxynitriles Promoted by Triflic Anhydride.

Justribó, V.; Pellegrinet, S. C.; Colombo, M. I. , J. Org. Chem. 2007, 72, 3702-3712

http://pubs.acs.org/doi/pdf/10.1021/jo062669f

 

Asymmetric Conjugate Addition of Alkynylboronates to Enones: Rationale for the Intriguing Catalysis Exerted by Binaphthols.

Pellegrinet, S. C.; Goodman, J. M., J. Am. Chem. Soc. 2006, 128, 3116-3117
http://pubs.acs.org/doi/pdf/10.1021/ja056727a

 

First Total Synthesis of (+)-Neplanocin B.

Comín, M. J.; Pellegrinet, S. C.; Rodríguez, J. B., Arkivoc 2005, XII, 205-213

 

Computer-Assisted Design of Asymmetric 1,3-dipolar Cycloadditions between Dimethylvinylborane and Chiral Nitrones.

Díaz, J.; Silva, M. A.; Goodman, J. M.; Pellegrinet, S. C., Tetrahedron 2005, 61, 10886-10893
http://dx.doi.org/10.1016/j.tet.2005.09.004

 

Computational Evaluation of Asymmetric Diels-Alder Reactions of Vinylboranes with Chiral Dienes.

Pellegrinet, S. C.; Silva, M. A.; Goodman, J. M. , Tetrahedron Lett. 2005, 46, 2461-2464
http://dx.doi.org/10.1016/j.tetlet.2005.02.050

 

A set of hands-on exercises on conformational analysis.

Pellegrinet, S. C.; Mata, E. G. 73-74, J. Chem. Ed. 2005, 82, 73-74



Research Projects

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Theoretical and Experimental Studies on Reactions of Organoboranes

  Units

Suipacha 531 - Rosario, Santa Fe.- Te: 54-341-4370477