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Silvina C. Pellegrinet    pellegrinet@iquir-conicet.gov.ar



Curriculum Vitae



Selected Publications

Allenylboronic Acid Pinacol Ester: A Selective Partner for [4 + 2] Cycloadditions

Labadie, N.; Ramos Marchena, J. M.; Medrán, N. S.; Pellegrinet, S. C. Org. Lett., 2021, 23, 5081-5085.


Theoretical Study of the Borono-Mannich Reaction with Pinacol Allenylboronate

Simonetti, S. O.; Pellegrinet, S. C. J. Org. Chem., 2020, 85, 7494-7500.

 

Remarkable Reactivity of Boron-Substituted Furans in the Diels-Alder Reactions with Maleic Anhydride

Medrán, N. S.; Dezotti, F.; Pellegrinet, S. C. Org. Lett., 2019, 21, 5068-5072. Virtual Issue "Celebrating Chemistry in Latin America" (Selected articles published in Organic LettersThe Journal of Organic Chemistry and Organometallics).

 

Asymmetric Organocatalytic C-C Bond Forming Reactions with Organoboranes: A Mechanistic Survey

Simonetti, S. O.; Pellegrinet, S. C. Eur. J. Org. Chem., 2019, 2956-2970.

 

Alkylhalovinylboranes: a new class of Diels-Alder dienophiles

Pisano, P. L.; Pellegrinet, S. C. RSC Adv., 2018, 8, 33864-33871.

 

Theoretical Study of the BF3-Promoted Rearrangement of Oxiranyl N-Methyliminodiacetic Acid Boronates

Vallejos, M. M.; Pellegrinet, S. C. J. Org. Chem.201782, 5917-5925.


α-Hydroxyacids accelerate the Diels-Alder reaction of dibutyl vinylboronate with cyclopentadiene: experimental results and mechanistic insights

Grimblat, N.; Sarotti, A. M.; Pisano, P. L.; Pellegrinet, S. C. New J. Chem., 2016, 40, 1966-1969. 

 

Diels-Alder reactions of pinacol alkenylboronates: an experimental and theoretical study

Vallejos, M. M.; Grimblat, N.; Pellegrinet, S. C. RSC Adv., 2014, 4, 36385-36400

 

A Hydrogen Bond Rationale for the Enantioselective β-Alkenylboration of Enones Catalyzed by O-Monoacyltartaric Acids

Grimblat, N.; Sugiura, M.; Pellegrinet, S. C. J. Org. Chem.201479, 6754-6758.

 

Theoretical investigation of the Diels-Alder reactions of unsaturated boronates

Grimblat, N.; Pellegrinet, S. C. Org. Biomol. Chem., 2013,11, 3733 - 3741.

 

Mechanistic Insights into the BINOL-Derived Phosphoric Acid-Catalyzed Asymmetric Allylboration of Aldehydes.

Grayson, M. N.; Pellegrinet, S. C.; Goodman, J. M., J. Am. Chem. Soc., 2012, 134, 2716-2722.

 

A facile microwave-assisted Diels-Alder reaction of vinylboronates.

Sarotti, A. M.; Pisano, P. L.; Pellegrinet, S. C., Org. Biomol. Chem. 2010, 8, 5069-5073

 

An experimental/theoretical approach to determine the optical purity and the absolute configuration of endo- and exo-norborn-5-en-2-ol using mandelate derivatives.

Pisano, P. L.; Sarotti, A. M.; Pellegrinet, S. C., Tetrahedron Lett. 2009, 50, 6121-6125

 

Mechanistic Insights into the Catalytic Asymmetric Allylboration of Ketones: Brønsted or Lewis Acid Activation?

Paton, R. S.; Goodman, J. M.; Pellegrinet, S. C., Org. Lett. 2009, 11, 37-40

 

A MultiStandard Approach for GIAO 13C NMR Calculations.

Sarotti, A. M.; Pellegrinet, S. C. J. Org. Chem., 2009, 74, 7254-7260, J. Org. Chem. 2009, 74, 7254-7260

 

Theoretical Study of the Asymmetric Conjugate Alkenylation of Enones Catalyzed by Binaphthols.

Paton, R. S.; Goodman, J. M.; Pellegrinet, S. C., J. Org. Chem. 2008, 73, 5078-5089

 

Asymmetric Conjugate Addition of Alkynylboronates to Enones: Rationale for the Intriguing Catalysis Exerted by Binaphthols.

Pellegrinet, S. C.; Goodman, J. M., J. Am. Chem. Soc. 2006, 128, 3116-3117



Research Projects

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Theoretical and Experimental Studies on Reactions of Organoboranes

  Units

Suipacha 531 - Rosario, Santa Fe.- Te: 54-341-4370477